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1.  Describe the formation of outer orbit complex [Ni (H2O)6]2+ ion using VBT


1. Draw the molecular orbital diagram for F2 molecule. Calculate the bond order and predict its magnetic property.


1. Describe bonding in [Mn (CN)6]3- using VBT

           State the hybridisation state of the metal, predict the geometry and magnetic property of the complex


Sodium chloride is produced from its elements through synthetic reaction. What mass of each reactant would be required to produce 25.0 mol of sodium chloride



Use the localised electron model to describe the bonding in hydrogen cyanide and phosgene (COCl2)


calculate the equilibrium solublility of silver arsenate in a solution that buffered to a ph of 3

Helium gas is contained inside a piston cylinder assembly as shown in the figure. Initially the gas is having pressure 1 bar and volume 0.01 m3. Then the current is supplied, and the gas is heated such that the final pressure is 1.2 bar and the final volume is 0.0145 m3

. 10 % of the electrical energy supplied to the gas is lost as heat from the cylinder. Determine the followings. If necessary, make assumption(s) with justification.

(a) How long the current is supplied if process is ideal?

(b) How long the current is supplied if process is real?


Helium gas is contained inside a piston cylinder assembly as shown in the figure. Initially the gas is

having pressure 1 bar and volume 0.01 m3. Then the current is supplied, and the gas is heated such that the final pressure is 1.2 bar and the final volume is 0.0145 m3

10 % of the electrical energy supplied to the gas is lost as heat from the cylinder. Determine the followings. If necessary, make assumption(s) with justification.

(a) How long the current is supplied if process is ideal?

(b) How long the current is supplied if process is real?


the class of drugs called statins reduced blood cholesterol levels by


Helium gas is contained inside a piston cylinder assembly as shown in the figure. Initially the gas is

having pressure 1 bar and volume 0.01 m3

. Then the current is supplied, and the gas is heated such

that the final pressure is 1.2 bar and the final volume is 0.0145 m3

. 10 % of the electrical energy

supplied to the gas is lost as heat from the cylinder. Determine the followings. If necessary, make

assumption(s) with justification.

(a) How long the current is supplied if process is ideal?

(b) How long the current is supplied if process is real?