Question #8634

calcium hydroxide is manufactured by heating calcium carbonate strongly to produce calcium oxide, and then adding a controlled amount of water to produce calcium hydroxide.
CaCO3(s)=CaO(s)+CO2(g)
CaO(s)+H2O(i)=Ca(OH)2(s)
a.) what mass of water would you produce from 1 tonne of calcium carbonate?
b.) what mass of water would you need to add to that calcium oxide?
c.) What mass of calcium hydroxide would you eventually produce?
(RAMs: H=1, C=12, O=16, Ca=40.)
1

Expert's answer

2012-04-20T11:34:48-0400

a)

It is impossible to produce water from calcium carbonate, but if you mean what mass of water is necessary to treatment of 1 tonne of calcium carbonate to calcium hydroxide, I found the solution (below).

The molar mass of calcium carbonate is M(CaCO3)=40+12+316=100 g/mol\mathrm{M}(\mathrm{CaCO}_3) = 40 + 12 + 3*16 = 100\ \mathrm{g/mol}

We have n(CaCO3)=m(CaCO3)/M(CaCO3)=1000000 g/100 g/mol=10000 mol\mathrm{n}(\mathrm{CaCO}_3) = \mathrm{m}(\mathrm{CaCO}_3)/\mathrm{M}(\mathrm{CaCO}_3) = 1000000\ \mathrm{g}/100\ \mathrm{g/mol} = 10000\ \mathrm{mol} of calcium carbonate.

CaCO3(s)=CaO(s)+CO2(g)\mathrm{CaCO}_3(\mathrm{s}) = \mathrm{CaO}(\mathrm{s}) + \mathrm{CO}_2(\mathrm{g}) (1)

CaO(s)+H2O(l)=Ca(OH)2(s)\mathrm{CaO}(\mathrm{s}) + \mathrm{H}_2\mathrm{O}(\mathrm{l}) = \mathrm{Ca}(\mathrm{OH})_2(\mathrm{s}) (2)

According to the equation (1) and (2) we need one mol of water for 1 mol of calcium carbonate, hence we have:

n(H2O)=n(CaCO3)=10000mol\mathrm{n(H_2O) = n(CaCO_3) = 10000mol}

The mass of water is:

m(H2O)=n(H2O)M(H2O)=10000mol18g/mol=180000 g=180 kg\mathrm{m(H_2O) = n(H_2O)*M(H_2O) = 10000mol*18g/mol = 180000\ g = 180\ kg}

b) The mass of water that you need to add to the calcium oxide is equal to previous solution.

M(water)=180 kg\mathrm{M(water) = 180\ kg}

c)

The molar mass of calcium carbonate is M(CaO)=40+16=56 g/mol\mathrm{M}(\mathrm{CaO}) = 40 + 16 = 56\ \mathrm{g/mol}

According to the equation (1) and (2) we need 1 mol of CaO for 1 mol of calcium carbonate, hence we have:

n(CaO)=n(CaCO3)=10000mol\mathrm{n(CaO) = n(CaCO_3) = 10000mol}

The mass of CaO is:

m(CaO)=n(CaO)M(CaO)=10000mol56g/mol=560000 g=560 kg\mathrm{m(CaO) = n(CaO)*M(CaO) = 10000mol*56g/mol = 560000\ g = 560\ kg}

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