1. A 1.000-g sample of ultrapure silicon was treated with an oxidizing agent and the resulting SiO2, after proper collection and drying, weighed 2.1387-g. Calculate the %Si in the sample.
Solution:
analyte = ultrapure silicon (Si)
precipitate = SiO2
FW Si = 28.0855 g/mol
FW SiO2 = 60.08 g/mol
a = 1
b = 1
Therefore,
GF = (28.0855 / 60.08) × (1/1) = 0.46747
GF = Grams of analyte / Grams of precipitate
Therefore,
Grams of analyte = GF × Grams of precipitate
Grams of Si = GF × Grams of SiO2 = (0.46747) × (2.1387 g) = 0.9998 g
%Si = (Mass of Si / Mass of sample) × 100%
%Si = (0.9998 g / 1.000 g) × 100% = 99.98%
%Si = 99.98%
Answer: The %Si in the sample is 99.98%
Comments
Leave a comment