A tank contains 78.0 g of N2 and 42.0 g of Ne at a total pressure of 3.75 atm and a temperature of 50.0°C. Calculate the following quantities.
(a) moles of N2
(b) moles of Ne
(c) the partial pressure of N2
(d) the partial pressure of Ne
Solution:
The molar mass of N2 is 28.0134 g/mol
The molar mass of Ne is 20.1797 g/mol
Calculate the moles of each gas:
(a): (78.0 g N2) × (1 mol N2 / 28.0134 g N2) = 2.7844 mol N2 = 2.78 mol N2
Moles of N2 = 2.78 mol
(b): (42.0 g Ne) × (1 mol Ne / 20.1797 g Ne) = 2.0813 mol Ne = 2.08 mol Ne
Moles of Ne = 2.08 mol
Dalton's law of partial pressures can be used.
Dalton's law can be expressed using the mole fraction of a gas, x: Pgas1 = xgas1 × PTotal
The mole fraction (x) of a gas is the number of moles of that gas divided by the total moles of gas in the mixture:
xgas1 = mole fraction of gas 1 = (Moles of gas 1) / (Total moles of gas)
Total moles of gas = Moles of N2 + Moles of Ne = 2.78 mol + 2.08 mol = 4.86 mol
Calculate the mole fraction of each gas:
xN2 = (Moles of N2) / (Total moles of gas) = (2.78 mol) / (4.86 mol) = 0.572
xN2 = 0.572
xNe = (Moles of Ne) / (Total moles of gas) = (2.08 mol) / (4.86 mol) = 0.428
xNe = 0.428
Calculate the partial pressure of each gas:
(c): PN2 = xN2 × PTotal = 0.572 × 3.75 atm = 2.145 atm
The partial pressure of N2 = 2.145 atm
(d): PNe = xNe × PTotal = 0.428 × 3.75 atm =1.605 atm
The partial pressure of Ne = 1.605 atm
Answers:
(a): Moles of N2 is 2.78 mol
(b): Moles of Ne is 2.08 mol
(c): The partial pressure of N2 is 2.145 atm
(d): The partial pressure of Ne is 1.605 atm
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