Solution:
(1):
phosphoric acid - H3PO4
(75.0 g H3PO4) × (1 / 50.0 mL) = 1.5 g/mL H3PO4
(2):
The molar mass of NaCl is 58.5 g/mol.
Thus,
(2 mol NaCl / 1 L) × (500 mL) × (1 L / 1000 mL) × (58.5 g NaCl / 1 mol NaCl) = 58.5 g NaCl
(3):
The molar mass of BaF2 is 175 g/mol.
Thus,
(0.350 g BaF2) × (1 mol BaF2 / 175 g BaF2) × (1 / 0.50 L) = 0.004 mol/L BaF2
(4):
The molar mass of NaOH is 40 g/mol.
Thus,
(10.0 g NaOH) × (1 mol NaOH / 40 g NaOH) × (1 / 250 mL) × (1000 mL / 1 L) = 1.0 mol/L NaOH
(5):
The molar mass of AgNO3 is 170 g/mol.
Thus,
(0.10 mol AgNO3 / 1 L) × (0.50 L) × (170 g AgNO3 / 1 mol AgNO3) = 8.5 g AgNO3
(6):
The molar mass of CuS is 95.6 g/mol.
Thus,
(23.9 g CuS) × (1 mol CuS / 95.6 g CuS) × (1 L / 1.0 mol CuS) = 0.25 L of solution
(7):
The equation for dilution calculations can be used.
where:
c1, V1 - the molarity and volume of the concentrated solution
c2, V2 - the molarity and volume of the diluted solution
Thus:
(6.0 mol/L) × (100 mL) = c2 × (500 mL)
c2 = (6.0 mol/L × 100 mL) / (500 mL) = 1.2 mol/L
c2 = 1.2 mol/L
(8):
The equation for dilution calculations can be used.
where:
c1, V1 - the molarity and volume of the concentrated solution
c2, V2 - the molarity and volume of the diluted solution
Thus:
(6.0 M) × V1 = (0.1 M) × (3.0 L)
V1 = (0.1 M × 3.0 L) / (6.0 M) = 0.05 L
V1 = 0.05 L
(9):
The molar mass of NaCl is 58.44 g/mol.
Thus,
(0.5 mol NaCl / 1 L) × (58.44 g NaCl / 1 mol NaCl) × (500 mL) × (1 L / 1000 mL) = 14.61 g NaCl
Steps of preparation of a 0.5 mol/L solution of sodium chloride (NaCl):
1. 14.61 grams of sodium chloride (NaCl) is weighed out and added to a 500 mL volumetric flask that has been about half-filled with distilled water.
2. The solution is swirled until all of NaCl dissolves.
3. More distilled water is carefully added up to the line etched on the neck of the flask (up to 500 mL).
4. The flask is capped and inverted several times to completely mix.
Answers:
1) 1.5 g/mL H3PO4
2) 58.5 g NaCl
3) 0.004 mol/L BaF2
4) 1.0 mol/L NaOH
5) 8.5 g AgNO3
6) 0.25 L of solution
7) c2 = 1.2 mol/L
8) V1 = 0.05 L
9) 14.61 g NaCl are dissolved in 500 mL volumetric flask.
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