An unknown oxalate, XC2O4, is found to be 41.72% O by mass. Identify the element, X.
Solution:
Suppose the molar mass of X is x, then:
M(XC2O4) = Ar(X) + 2×Ar(C) + 4×Ar(O) = x + 2×12.0107 + 4×15.999 = x + 88.0174 (g/mol)
Hence,
w(O) = [4×Ar(O) / M(XC2O4)] × 100%
0.4172 = 4×15.999 / (x + 88.0174)
x + 88.0174 = 153.394
x = 65.376 (g/mol)
The molar mass equal to 65.376 g/mol corresponds to the element - zinc (Zn).
Thus: XC2O4 = ZnC2O4 - zinc oxalate
Answer: Element X is zinc (Zn).
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