What is the empirical formula if 38.23 % Oxygen, 50.61 % Cu, and 11.16 % Nitrogen?
Solution:
Molar mass of oxygen (O) is 15.999 g mol-1.
Molar mass of copper (Cu) is 63.546 g mol-1.
Molar mass of nitrogen (N) is 14.0067 g mol-1.
Assume a 100g sample, convert the same % values to grams.
Hence,
Mass of O = w(O) × Mass of sample = 0.3823 × 100 g = 38.23 g
Mass of Cu = w(Cu) × Mass of sample = 0.5061 × 100 g = 50.61 g
Mass of N= w(N) × Mass of sample = 0.1116 × 100 g = 11.16 g
Convert to moles.
38.23 g O × (1 mol O / 15.999 g O) = 2.3895 mol O
50.61 g Cu × (1 mol Cu / 63.546 g Cu) = 0.79643 mol Cu
11.16 g N × (1 mol N / 14.0067 g N) = 0.79676 mol N
Divide both moles by the smallest of the results.
O: 2.3895 / 0.79643 = 3.000
Cu: 0.79643 / 0.79643 = 1.000
N: 0.79676 / 0.79643 = 1.000
The empirical formula of the compound is CuNO3
Answer: The empirical formula of the compound is CuNO3.
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