The mass of the silver can be calculated from its molar mass "M" (107.87 g/mol) and its number of the moles "n":
"m = M\u00b7n" .
According to the definition of the Avogadro's number "N_A = 6.022\u00b710^{23}" , one mole of substance contains "N_A" of its formula units. Therefore, the number of the moles of silver is its number of atoms divided by Avogadro's number:
"n =\\frac{N}{N_A} = \\frac{4.56\u00b710^{21}}{6.022\u00b710^{23}} = 7.57\u00b710^{-3}" mol.
Finally, the mass of the silver is:
"m = 107.87\\text{ g\/mol}\u00b77.57\u00b710^{-3}\\text{ mol} =0.817" g.
Answer: if you have 4.56 x 10^21 atoms of silver, the mass of the silver is 0.817 g.
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