Answer to Question #113853 in Chemistry for DEEPAK SINGH

Question #113853
Calculate the molar refractivity of allyl chloride at a temperature at which it's density is 0.938g cm^-3 the experimentally observed value of refractive index at this temperature is 1.3715.
1
Expert's answer
2020-05-07T14:09:02-0400

Solution:

CH2=CHCH2Cl or C3H5Cl - allyl chloride

The molecular weight of allyl chloride is 76.52 g/mol.


The molar refractivity [R] (cm3 mol-1) is a constitutive-additive property that is calculated by the Lorenz-Lorentz formula:



where M is the molecular weight, n it is the refraction index and p the density.

Therefore,




Answer: The molar refractivity of allyl chloride is 18.52 cm3 mol-1.

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