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8ml of hydrochloric acid is added to 10ml of a 1M soda. After this addition, the measure of the molar concentration of H30+ ion gives 10-7M. What is the concentration in mol/l of the acid solution?

Which of the following acids is the strongest?

A. HCN;pKa(HCN/CN3-)=9.2

B. HNO2;pKa(HNO2/NO2)=3.3

C. H3PO4;pKa(H3PO4/H2PO4-)=2.1

D. H2CO3;Ka(H2CO3/HCO3-)=4.5x10-7

E. H2SO3;Ka(H2SO3/HSO3-)=1.7x10-2

Estimate the work involved when 1 mole of an ideal gas at 25
Predict the Normality of H2SO4 if 75 ml of 96.6 % pure H2SO4 added to 425 ml water. The density of H2SO4 is 1.83 g/cm3?
Predict the Normality of H2SO4 if 75 ml of 96.6 % pure H2SO4 added to 425 ml water. The density of H2SO4 is 1.83 g/cm3?

One mole of an ideal gas at 300K expands isothemally from 5.00 dm3 to 10.00dm3. Calculate the work done if the expansion is reversible


Derive the Clausius-clapeyron equation

 An engine containing 2 kg air as working substance is initially at 1 atm and 27 0C. 

The system undergoes isochoric process to a point where pressure of the system is 2 

atm. At this point heat is transferred to the air untill the volume doubles. Calulate 

the total workdone and the amount of heat transferred to the air


. A spring of mass 2 kg and stiffness 1 kN/m is dropped from a height of 2 mm on the ground. Calate the madrum Odave heigh which the spring is compressed.
Gas is compressed slowly and isothermally at 300K from 1 bar to 8 bar. Calculate

the work done using the given state of equation. (B = -5.397 X 10-6 m3

/mol)

(note: volume at each stage should be near to the ideal gas volume)



PV

RT = 1 +

B

V
Using the following data, calculate the amount of energy by which benzene is more

stable as compared to one Kekule structure:



∆fH*=(methane, g) = −84.85 kJ/mol

∆fH*=(ethane, g) = −94.85 kJ/mol

∆fH*=(ethylene, g) = −65.35 kJ/mol

∆fH*=(benzene, g) = −98.45 kJ/mol



C (graphite) → C (g); ∆H* = 714.39 kJ/mol



H2(g) → 2H(g) ∆H* = 435.89 kJ/mol



(here '*' denotes degree sign)
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