Question #81533

For the reaction IO3- + 5I- + 6H+ → 3I2 + 3H2O the rate of disappearance of I- at a particular time and concentration is 5.0 x 10-3 Ms-1. What is the rate of disappearance of H+ in Ms-1?
6.0 x 10-3
3.0 x 10-3
-5.0 x 10-3
1.0 x 10-3
5.0 x 10-3

Expert's answer

Question #81533, Chemistry / Physical Chemistry

Question:

For the reaction IO3−+5I−+6H+→3I2+3H2O\mathrm{IO3 - + 5I - + 6H + \rightarrow 3I2 + 3H2O} the rate of disappearance of I−I^- at a particular time and concentration is 5.0×10−3 Ms−15.0 \times 10^{-3} \mathrm{~Ms^{-1}}. What is the rate of disappearance of H+H^+ in Ms-1?

- 6.0 x 10⁻³

- 3.0 x 10⁻³

- -5.0 x 10⁻³

- 1.0 x 10⁻³

- 5.0 x 10⁻³

Solution:

V=(−1/5)∗(\dc(I−)/dt)=(−1/6)∗(\dc(H+)/dt)V = (-1/5)^* (\dc(I^-) / dt) = (-1/6)^* (\dc(H^+) / dt)


Let \dc(H+)/dt=x\dc(H^+) / dt = x, then


(−1/5)∗5.0×10−3=(−1/6)∗x(-1/5)^* 5.0 \times 10^{-3} = (-1/6)^* xx=6.0x10−3x = 6.0x 10^{-3}


Answer: (\dc(H+)/dt)=6/0×10−3(\dc(H^+) / dt) = 6/0 \times 10^{-3}

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