Question #81533

For the reaction IO3- + 5I- + 6H+ → 3I2 + 3H2O the rate of disappearance of I- at a particular time and concentration is 5.0 x 10-3 Ms-1. What is the rate of disappearance of H+ in Ms-1?
6.0 x 10-3
3.0 x 10-3
-5.0 x 10-3
1.0 x 10-3
5.0 x 10-3
1

Expert's answer

2018-10-03T05:02:18-0400

Question #81533, Chemistry / Physical Chemistry

Question:

For the reaction IO3+5I+6H+3I2+3H2O\mathrm{IO3 - + 5I - + 6H + \rightarrow 3I2 + 3H2O} the rate of disappearance of II^- at a particular time and concentration is 5.0×103 Ms15.0 \times 10^{-3} \mathrm{~Ms^{-1}}. What is the rate of disappearance of H+H^+ in Ms-1?

- 6.0 x 10⁻³

- 3.0 x 10⁻³

- -5.0 x 10⁻³

- 1.0 x 10⁻³

- 5.0 x 10⁻³

Solution:

V=(1/5)(\dc(I)/dt)=(1/6)(\dc(H+)/dt)V = (-1/5)^* (\dc(I^-) / dt) = (-1/6)^* (\dc(H^+) / dt)


Let \dc(H+)/dt=x\dc(H^+) / dt = x, then


(1/5)5.0×103=(1/6)x(-1/5)^* 5.0 \times 10^{-3} = (-1/6)^* xx=6.0x103x = 6.0x 10^{-3}


Answer: (\dc(H+)/dt)=6/0×103(\dc(H^+) / dt) = 6/0 \times 10^{-3}

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