From the following molar conductivities at infinite dilutions
^°m for Ba(OH)2 = 457.6 ohm-1cm2mol-1
^°m for Bacl2= 240.6 ohm-1cm2mol-1
^°m for NH4cl = 129.8 ohm-1cm2mol-1
Calculate the ^°m of NH4cl
°m of Ba(OH)2 is 457.6 ohm-1*cm2*mol-1;
°m of BaCl2 is 240.6 ohm-1*cm2*mol-1;
°m of NH4Cl is 129.8 ohm-1*cm2*mol-1;
The °m of NH4Cl is 129.8 cm2*ohm-1*mol-1;
Probably should calculated the °m of NH4OH.
Then, NH4OH = NH4+ + OH-;
So, °m(NH4OH) = °m(NH4+) + °m(OH-);
Or °m(NH4OH) = °m(NH4Cl) - (1/2 * °m(BaCl2)) + (1/2 * °m(Ba(OH)2)) = ((°m(NH4+) + °m(Cl-)) - (1/2 * ( °m(Ba2+) + 2 * °m(Cl-))) + (1/2 * ( °m(Ba2+) + 2 * °m(OH-))) = °m(NH4+) + °m(Cl-) - 1/2 * °m(Ba2+) - °m(Cl-) + 1/2 * °m(Ba2+) + °m(OH-) = °m(NH4+) + °m(OH-).
So:
°m(NH4OH) = °m(NH4Cl) - (1/2 * °m(BaCl2)) + (1/2 * °m(Ba(OH)2) = 129.8 - (1/2 * 240.6) + (1/2 * 457.6) = 129.8 - 120.3 + 228.8 = 238.3 cm2*ohm-1*mol-1.
Answer: 238.3 cm2*ohm-1*mol-1.
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