Answer to Question #145807 in Physical Chemistry for deepak

Question

Hydrogen gas at 1 atm pressure is bubbled through Ni2+ ions present in a purified solution
(obtained after solvent extraction). If the activity of Ni2+ in solution is 0.3, determine the minimum
pH required to precipitate Ni from the solution at 25oC. {Data: Standard oxidation potential for
H2/2H+ and Ni/Ni2+ are 0.0 V and 0.25 V respectively, R = 8.314 J/mol/K, Faraday constant = 96500
Coulomb/gm eqv wt}.

Answer 1

E(Ni²⁺/Ni) = -0.25 + RT/(2F)*ln(a(Ni²⁺)) = -0.25+8.314*(25+273)/(2*96500)*ln(0.3) = -0.265

E(Ni²⁺/Ni) = E(H⁺/H₂)

E(H⁺/H₂) = RT/F*ln(a(H⁺)/p(H₂)^0.5)

-0.265 = 8.314*(25+273)/96500*(-2.30*pH)

pH = 4.49