Question #111787
define the term van't hoff factor.
1
Expert's answer
2020-04-24T13:36:05-0400

Answer: The van't Hoff factor ii is a dimensionless parameter that describes the behavior of the substance in the solution. This parameter is numerically equal to the ratio of the value of some colligative property (e.g. boiling point change Tbp∆T_{bp}, melting point change Tmp∆T_{mp}, osmotic pressure π\pi) of the solution of this substance to the value of the same colligative property of a non-electrolyte solution with the same concentration, when all the other conditions are the same:


i=Tbp,slnTbp,nel.sln=Tmp,slnTmp,nel.sln=πslnπnel.slni = \frac{∆T_{bp,sln}}{∆T_{bp, nel.sln}}= \frac{∆T_{mp,sln}}{∆T_{mp, nel.sln}} = \frac{\pi_{sln}}{\pi_{ nel.sln}}

The van't Hoff factor can be calculated using the degree of dissociation α\alpha of the solute which formula unit contains nn ions:


i=1+α(n1).i = 1+\alpha(n-1).

For the strong electrolytes, the degree of dissociation α\alpha is unity and the van't Hoff factor is equal to the number of ions in the formula unit nn : i=ni=n .


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