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1.) Which is the best fuel: methanol, propanol or butanol? Explain with the use of the concept


of thermochemical equations and heats of reaction.


2.) Using Hess’ Law, propose a series of steps for the reaction of nitrogen dioxide gas and


liquid water to form aqueous nitric acid and nitrogen monoxide gas. What is the enthalpy


of reaction?

1. Two bottles at the same temperature containing hydrogen sulphide (H2S) and ammonia (NH3) are placed at equal lengths from you and are opened at the same time. Which gas would you smell first?

A student wants to study a certain integral membrane protein, for example, a Na+ -K+ pump. Give details on the kinds of difficulty he/she would run into. Explain how it will be different from studying water-soluble globular proteins.



calculate normality and titre of koh -solution (volume 5.45 ml) if it is necessary for the titration 6.7 ml h2so4-solution with cn=0.1025 mol/l


A solution of HClO4 was standardized by dissolving 0.4008 g of primary-standard-grade HgO in a solution of KBr:



HgO(s) + 4Br- + H2O οƒ  HgBr42- + 2OH-



The liberated OH- consumed 43.75 mL of the acid. Calculate the molar concentration of the HClO4.


Balance in acidic medium. Show step by step process.

Iron (solid) reacts with hydrochloric acid (liquid) to form aqueous iron(II) chloride and gaseous


hydrogen.


1. Balance in acidic medium. Show step by step process.

Iron (solid) reacts with hydrochloric acid (liquid) to form aqueous iron(II) chloride and gaseous hydrogen.

2. Balance in acidic medium. Show step by step process.

𝑁𝑂2βˆ’ + 𝐴𝑙(𝑠) β†’ 𝑁𝐻4+ (π‘Žπ‘ž)

(π‘Žπ‘ž)

+ 𝐴𝑙𝑂2βˆ’

(π‘Žπ‘ž)

3. Balance the following reaction in basic medium. Show step by step process.

𝑆 𝑂2βˆ’ + 𝑁𝑖(𝑂𝐻) β†’ 𝑆𝑂2βˆ’ + 𝑁𝑖𝑂

2 8(π‘Žπ‘ž) 2(𝑠) 4(π‘Žπ‘ž) 2(𝑠)


Suppose that a machine part requires 400 mg of copper to provide a coating that is thick enough for a certain electrical function. If you run an electrolysis using copper(II) ions for 10 minutes at a current of 0.5 A, will you meet the requirement?

The following questions pertain to a voltaic cell in which the following half-reactions occur: S (s) + 2e- οƒ  S2- (aq) Ca2+ (aq) + 2e- οƒ  Ca (s) a. Which half-reaction will proceed as a reduction? Which will proceed as an oxidation? How do you know? b. Rewrite the half-reactions in the correct directions. c. Write a balanced equation for the overall cell reaction. d. Calculate the cell potential.Β Β 


A hypothetical acid HA has a dissociation constant 1.8 π‘₯ 10^-3

. a. Write a balanced dissociation reaction of the acid

b. Write the equilibrium constant expression for the acid

c. If the initial concentration of the acid is 0.5 M, determine its hydrogen ion concentration.

d. Calculate the ionization constant

e. Comment on the strength of the acid.


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