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Explain why the 2-hydroxy-2-methylbutanoic acid produced in this reaction is not optically active.

(The reaction is the incomplete mechanism in the conversion of Butanone into 2-hydroxy-2-methylbutanoic acid)


Give two reasons why methanol, synthesised from carbon dioxide and hydrogen, may not be a completely carbon-neutral fuel.


The high resolution proton nmr spectrum of propan-1-ol contains four peaks. What is the splitting pattern of the four peaks?

A. 3 2 2 1

B. 3 4 3 1

C. 3 6 3 1

D. 3 6 4 2


Reactions of Alkenes

Solve for one major organic product given the following combination of reactants (substrate+reagents)


Substrate: C7H12

Reagent: H2/Pt


Reactions of Arenes

Solve for one major organic product given the following combination of reactants (substrate+reagents).


Substrate: 4-Isopropylbenzoic acid

Reagents: Br2, FeBr3


What is the pH of a 0.350 M solution of lithium citrate? (Ka Citric Acid = 7.4 x 10-4


What is the pH of a 1.15 M solution of methanoic acid? Ka = 1.8 x 10-4?


25cm³ of a solution containing 4.4grams/litre sodium hydroxide was required to neutralize 17.8cm²of a propanoic acid . Determine the concentration of the propanoic acid in gram's/litre?


Calculate the percentage purity of CaCO3 when 50g of marble reacts with an excess of HCl to make 15 g of CO2.


Instant hot packs work by crystallizing sodium acetate (NaCH3COO). The molar enthalpy of crystallization for sodium acetate is -56.7 kJ/mol. How many grams of sodium acetate are needed to warm 125.0 ml of water from 21 degrees C to 35.4 degrees C?


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