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Different enantiomers are metabolised differently by the body. The monosaccharide below has been patented proposed as a low-calorie sweetener. Do a D and L assignment for the enantiomer below, explain your assignment and how this would affect the calorific value of the rhamnose isomer. Provide an explanation for the following:

1.    Would the monosaccharides below more likely adopt a pyranose or furanose?

2.    Is the sugar considered a reducing sugar?

3.    Would the optical rotation of the enantiomer below change in the solution?


Stereochemistry of ethynylcyclohexane + excess HBr


structure of the major products of ethynylcyclohexane + excess HBr with proper configuration


chemical equation for the reaction of ethynylcyclohexane + excess HBr


Stereochemistry of 1-methylcyclohexene + Br2 in CCl4


structure of the major products of 1-methylcyclohexene + Br2 in CCl4 with proper configuration


chemical equation for the reaction of 1-methylcyclohexene + Br2 in CCl4


an amonium alkansic acid salt on analysis give the following results

% c = 60.5

% h = 6.65

If 0.309 of the salt product 0.0313g of nitrogen. Determine the empirical formula of the salt


on analysis, a certain organic compound was found to contain 41% carbon, 8% hydrogen and the rest is oxygen. if it's molecular mass was 64g, find it's empirical formula


A barrel of crude oil has a volume of 42 gallons, only approximately 45% of which is processed into gasoline. If your car achieves 33 mi/gal, and you drive 36,000 miles in one year, how many barrels of crude oil are required to run your car for a year?


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