Different enantiomers are metabolised differently by the body. The monosaccharide below has been patented proposed as a low-calorie sweetener. Do a D and L assignment for the enantiomer below, explain your assignment and how this would affect the calorific value of the rhamnose isomer. Provide an explanation for the following:
1. Would the monosaccharides below more likely adopt a pyranose or furanose?
2. Is the sugar considered a reducing sugar?
3. Would the optical rotation of the enantiomer below change in the solution?
1.Pyranose since the pyranose ring is formed by the reaction of the hydroxyl group on carbon 5 (C-5) of a sugar with the aldehyde at carbon 1. This forms an intramolecular hemiacetal.
2. Yes since it is oxidised by mild oxidising agents.
3.No.
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