Answer to Question #88816 in Organic Chemistry for rebaone

Question #88816
complete the structure of zn(hg) , hcl ,oh with clemenson reduction
1
Expert's answer
2019-05-01T04:29:08-0400

The Clemmensen reduction is performed by heating an aldehyde/ketone with zinc amalgam (Zn-Hg) in aqueous HCl (see image attached).

The mechanism of the Clemmensen reduction is not much known. One thing reasonably certain is that the corresponding alcohols are not intermediates, since alcohols prepared in other ways fail to give the reaction [March’s advanced organic chemistry reactions, mechanisms, and structure, 7th Edition. Michael B. Smith, 2013, p. 1543]. Thus, alcohols are not substrates of the mentioned reaction.


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