1. (B.P 341.9K) + heptane (B.P.371.6K)
Mixture is separated by fractional distillation because of a difference in their boiling point is very less.
2. (B.P. 351K) + ether (B.P.307.6K)
Simple distillation - method to separate out mixture of two liquids where the difference in boiling point is large.
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