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Answer to Question #165364 in Organic Chemistry for George

Question #165364

Give the reagents and reaction conditions for the formation of nitrobenzene from benzene

Give the mechanism for this reaction.


1
Expert's answer
2021-03-08T06:13:11-0500

The nitration of benzene occures in strongly acidic conditions while heating. The nitrating mixture is 2 moles of concentrated H2SO4 per 1 mol concentrated HNO3. The nitrating particle, NO2+, appeares in the following reaction: 2H2SO4 + HNO3 = NO2+ + H3O+ + 2HSO4-

The mechanism of the nitration reaction is following:


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