Out of these two compounds only CaCO3 decomposes upon heating according to the reaction
CaCO3 --> CaO + CO2
Therefore,
mCaCO3=44gCO2/mol0.44gCO2×1molCO21molCaCO3×1molCaCO3100.1gCaCO3=1.0g
%CaCO3=3.0g1.0g×100%=33%
%Na2CO3=100−33=67%
Answer: 67%
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