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Answer to Question #111007 in Organic Chemistry for kylie
Question #111007
Which of the following alcohols is the LEAST soluble in water?
(1) CH3OH
(2) CH3CH2OH
(3) CH3(CH2)3OH
(4) (CH3)2CHCH2OH
(1) CH3OH
(2) CH3CH2OH
(3) CH3(CH2)3OH
(4) (CH3)2CHCH2OH
Expert's answer
(3) CH3(CH2)3OH
Butanol (CH3(CH2)3OH) is the least soluble in water. It has a higher number of carbons compared to methanol (CH3OH) and ethanol (CH3CH2OH). As a result, it forms more significant hydrophobic interaction. Similarly, the hydrophobic interaction of linear alcohols (butanol) is higher compared to branched alcohols (isobutanol, (CH3)2CH2CH2OH).
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