Hydroboration of styrene followed by oxidation with hydrogen peroxide leads to the formation of compound A. Oxidation of styrene with potassium permanganate in an acidic medium results in compound B. Compounds A and B can react with each other under acidic catalysis to form compound C.
What is the volume of carbon dioxide (molar volume of ideal gas Vm = 22.4 L/mol), released during the complete combustion (in excess of O2) of 5.00 grams of compound C?
a) 7.00 L
b) 7.43 L
c) 7.67 L
d) 8.02 L
e) 8.31 L
What is the oxidation number of Manganese in MnO4-?
What is the oxidation number of sulphur in S4O62- ?
What are the significances of the percentage composition of essential oils?
1. Fe3+ + e- → Fe2+ Eo = +0.77 V
Fe2+ + 2e- → Fe Eo = -0.44 V
Describe selection rule and intensities
Given that Eo for the reaction below is +1.51 V,
(a) calculate the reduction potential, E, in a solution of pH 2.5 and in which the ratio [Mn2+]:[MnO4-] = 1: 100.
(b) Show that E = +1:25 V when pH ¼ 3.0 and the ratio [Mn2+]:[MnO4-] =1:100.
(c) For a ratio [Mn2+]:[MnO4-]=1000 : 1, what must the pH of the solution be to give a value of E = +1.45 V?
(d) For a ratio [[Mn2+]: [MnO4-]=1 : 100, determine E in a solution of pH 1.8.