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2. The equilibrium constant for the reaction A → M is 0.2 at 300K. Calculate ∆G and ∆G0
for the
production of 1 mole of M at a pressure of 1 atm from A at a pressure of 20 atm and predict the
nature of the reaction under this condition�
Question – 9
(a) Chlorophyll the green colouring matter of plants contains 2.71% of
magnesium by mass. Calculate the number of magnesium atoms in
3.50 g of chlorophyll. [2.5]
(b) Commercially available aq.Conc.HCl is 38% by mass. Calculate the
molarity of solution.(d=1.19 g/ml). What volume of conc. HCl is
required to make 1L of 0.10 M HCl ? [2.5]
Question – 10
(a) 1.18 g of a mixture of Na2CO3 & K2SO4 is present in 250 ml aqueous
solution. 25 ml of this solution is completely neutralized by 20 ml of
0.05 M H2SO4. Calculate the percentage composition of the
mixture. [2.5]
(b) 4.15 g of an acid are dissolved in water and volume of solution is
made 500 ml by adding water . 20 ml of this solution require 20 ml
of N/10 NaOH solution . If the acid is dibasic, calculate the molar
mass of acid.

boron occurs in nature in the form of two isotopes having atomic mass 10 and 11. what are the precentage abundances of two isotopes in a sample of boron haqving atomic mass 10.8


Write the principles involved in the estimation of fe2+ ion using k2cr2o7
Study of MO diagram for heteronuclear diatmoic molecules

The pH at 250C of a mixture of 20 ml hydrochloric acid (pH1=2) with 30 mL of the same acid (pH2=3) is:

A. 5

B. 2.5

C. 1

D. 2.3


ALuminum sulphide is produced from a reaction of the elements Al and S according to the reaction 2Al(s) + 3S(g)  → Al2S3 . Given that the mass of aluminum is defined by a function mA such that t(mAl) = [ mAl 4.1

41/10 mAl ] and that t( mAl ) is a singular matrix. The mass of sulfur that reacted was equivalent to the POH of 3.981 x 10-7M solution of a base. What is the mass of the product formed?

A. 10.41g B. 102.6g C. 25.2g D. 40.5g



Radioactive decay involves the emission of n aplha particles and m beta particles. Given that the decay process involves the reaction 714N  → n24He +m0-1β + n1n2X. Given that the values of n1,n2 , n and m are calculated theoretically such that n1 - m(d/dy (1/y)) = 7 where y=-1.

A. n2 = 14-n

B. n1 = 7

C. n2 =14-3n

D. m=2n

E. n1 = 7-2m + n


The electronic configuration of an atom's valence shell is ns2np2. During the titration of a CuCl2 with conc. H2SO4(0.1M) acid and a suitable indicator was used such that PH(y) of the HCl was 1.500. What is the period to which the element belongs with respect to the fact that y= -log(10+10n/2)



Quantum numbers are always in the order n,l,ml, ms. Which of the following quantum numbers is likely NOT to occur and why?

A. 0,2,3,4 because the principal quantum number belongs to natural numbers

B. 2,1,-2,+1/2 because the spin quantum number ranges from -l to l

C. 3,2,1,-1/2/ beacuse the magnetic quantum number is always negative

D.4,3,-4,+-1/2 because the azimuthal quantum number is always a fraction.



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