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30.The requirement that the ground state configuration of an atom is generated by filling 

electrons into orbitals from lowest energy to the highest energy observing the 

maximum number allowed for each of these level is 

a) The aufbau’s principle

b) Bustemente’s principle

c) Hund’s rule

d) The pauli’s principle 


1.      Draw structure of a tertiary alcohol, give its correct name and the show the REACTION MECHANISM for the formation of an alkyl halide from this alcohol.                                  

HINT: 

-      The reaction is SN1, it takes place through 3 STEPS and TWO carbocations forms as intermediates. 

-      The reaction was carried in the presence of an acid and in the presence of halide ions, and not at elevated temperature.

-      Halide ions are good nucleophiles (they are much stronger nucleophiles than water), and since halide ions are present in high concentration, most of the carbocations react with an electron pair of a halide ion to form a more stable species, the alkyl halide product.




 

 Why would water be considered an alcohol derivative?


Calculation the equilibrium concentration of NO2 in a solution prepared by dissolving 0.2 mol of N2O4 in 400ml of cloroform. For the reaction N2O4 NO, in chloroform, k=1.07×10^-5
(b) what will be the percentage decomposition of the original N2O4

At STP, 30cm*3 of H2 gas was burnt in excess oxygen gas. if the final volume of gases in the reaction was 100cm*3., what was the initial volume of the oxygen?


What is hydrogen


the uv spectrum of acetone shows two peaks at lambda max = 189 and is 273 nm.identify the electronic transition for each peak
The symmetrical breathing mode of SF6 is ramN active . Can this vibration be from detected in the aIR spectrum? If yes why? And if no why not
the molecular transition 0.0001 K Cal/mol to order to occur.indicate the spectral region in which you would expect the absorption of radiation and calculate the wavelength
sketch H nmr spectrum H3Ge-PH2
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