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Find the value for solution with pH=7.0 and pe = 8.0 for the concentration of Fe2+, if the solution is in equilibrium with solid ferric hydroxide.



Find the value for solution with pH=7.0 and pe = 8.0 for the following.

  1. (Fe3+)/(Fee+) ratio
  2. (NO3-)/(NH4+) ratio

Express the oxidation and reduction balanced overall reactions for the following.

  1. (HOCI+HS-) to (Cl-+SO42-)
  2. (CH3OH+O2(aq) to (CO2(g)+H2O(I))
  3. (MnO4-+) to MnO2(s)

Express the oxidation and reduction half reactions of the following.

  1. (HOCI+HS-) to (Cl-+SO42-)
  2. (CH3OH+O2(aq) to (CO2(g)+H2O(I))
  3. (MnO4-+) to MnO2(s)

Express the average oxidation state of C in the following:

  1. CH4
  2. CH2O
  3. CO
  4. CH3CHOHCOOH

2. The pH of a 0.0516 M solution of nitrous acid, HNO2, is 2.34. What is its Ka?

1. What is the pH of a solution of HCl with a concentration of 1.2 X 10-3 M?

2. Calculate:



a. The rate constant for the radioactive disintegration of cobalt-60, an isotope used in



cancer therapy.



60Co27 decays with a half-life of 5.2 years to produce



60Ni28.



b. The fraction and the percentage of a sample of the 60Co27 isotope that will remain



after 15 years.



c. How long it takes for a sample of 60Co27 to disintegrate to the extent that only 2 % of



the original amount remains?



d. The half-life of 216Po84 is 0.16 s. How long does it take to reduce a sample of it to the



negligible amount of 0.000010 % of the original amount (1.0 x 10



-7



times the original



amount)?�

The reduction potential for Na (-2.71 V) is lower than that of the elements above it (Li, -3.04 V) and below it (K, -2.93 V). Explain the lack of a clear trend in the redox properties of the first 3 alkali metals. 


Aspirin (C9H8O4) in the form of a spherical tablet has a diameter of 0.04 inch. if the sample has a density of 1.4 g/cm3 How many carbon atoms does it contains?

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