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A gas is initially  at volume 40.0 L, pressure 600 mmHg and temperature 35 °C. Calculate the final pressure of the gas in atm if the volume and temperature are changed to 2500 mL and 225 K, respectively.

Which of the reactions causes an increase in the temperature in the stratosphere? (A) (B) O(g) + O: (g) 0,"(g) O(g) + M (g) 0₁ (g) + (C) (D) O(g) + №z (g) - N O₂ (g) hv 20 (g) (g) (E) All of the above

What set of element contains a metalloid

Consider one mole of H2O(g) which occupies 20 L at 1 atm. Condensation of H2O(g) at 1 atm releases 30.22 kJ/mol of heat to the surrounding. Given that the density of H2O(l) at 373 K is 0.925 g/cm3 , calculate the change in the internal energy for the condensation of one mole of water at 1 atm and 373 K.


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“A photon from visible region of light has enough energy to excite an electron from the ground state of hydrogen atom to its fourth excited state.” Comment on the correctness of the above sentence. Provide mathematical support.


Sketch diagrams of the dπ-pπ bonds in Cl3PO and ClO4-. Draw the Lewis diagram for each and then designate the pπ-donor atoms (and their donor orbitals) and the dπ-acceptor atoms (and their acceptor orbitals).                                                                                     


(a)   Explain the trends in ionization and promotion energies of noble gases. Use chemical equations to discuss the observations that led to the synthesis of xenon compounds. 



Explain the C−C bonds lengths and bond order in the following: diamond, ethylene, benzene and graphite. Briefly state the nature of zeolites and of molecular sieves.


Draw the chemical structure of [Mn2(CO)10]. Explain how does it follow the 18 electron rule.                                                               


Compare and comment on the difference in the single-bond energies for the elements  of the second and third period of the following groups: group 14: C−C > Si−Si; but in Group 15: N−N < P−P; in Group 16: O−O <S-S and in group 17: F−F <Cl−Cl.          


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