3. The Henry’s law constant for H2S is 0.1 mole/L.atm and
H2S <---> HS- + H+
Where Ka = 10-7. The equilibrium pH of the solution is 4.5 if pure H2S gas is dissolved in water. Find the partial pressure of the H2S gas above the solution.
4. At a wastewater treatment plant, FeCl3(s) is added to remove excess phosphate (PO4-3) from the effluent. Assume the following reactions occur:
FeCl3(s) <---> Fe3+ + 3Cl-
FePO4(s) <---> Fe3+ + PO4-3
The Ksp for the second reaction is . What concentration of Fe3+ (in mg/L) is needed to maintain the phosphate concentration below the limit of 1 mg/L P?