"1)\\ 2Al \\ +""6HBr\\to" "2AlBr_3+3H_2"
Since 2 moles aluminium are required for every 6 moles of hydrogen bromide, yet we only have 3.22 moles aluminium and 4.96 moles of hydrogen bromide , it implies that HB"r" will get used up first and hence it is limiting reactant while Al is in excess.
So all 4.96 mol of HBr is used up and reacts with"\\ =\\dfrac{4.96}{3}=1.653 \\ mol Al" to produce"=\\dfrac{4.96}{2}=2.48\\ mol H_2"
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