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Form the covalent bonds between the C and four F atoms tell the bonds they form.


Show by calculation which process produces more energy per gram of material reacting:

 Fission of U-235: 92U

235 + 0 n

1 → Zr 40

94 + 58Ce 140 + 6 −1e

0 + 2 0 n

1

 

 

 Fusion of deuterium:1H

2 + 1H

2 → 1H

3 + 1H

1

 Nuclear mass for Ce-140 is 139.8734 and for Zr-94 is 93.8841.


The standard electrode potential for the Fe2+ ↔ Fe3+ + e – half reaction is -0.770 V. a) 

Using the Nernst equation [ E = E°− ( 0.059/n) log [Oxid]/[Red]] calculate the voltage of this 

half-cell when the [Fe3+] is 1.0 x 10 -3 and [Fe2+] is 1.0 x 10 -1

. b) Calculate the approximate 

equilibrium constant (K) for the half reaction.


Titanium is manufactured by heating titanium(iv) chloride with sodium. TiCl4(g) + 4Na(l) ->Ti(s) + 4NaCl(s) 

What mass of sodium is required to produce 1 tonne of titanium




As a chemical engineer you need to pump the products without affecting products properties.

Because the flow properties will affect the fluid properties of the products like density and

viscosity. Pumping without destroying product integrity is as important as the heat

exchanger that comes after the pump. The piston pumps can handle very delicate and

viscous food stuffs and can pump up to very high pressure without damaging the food

particles. It can also be applied very successfully in heavy duty applications for industries

other than the food industry.

Answer the following

Pump Can work empty (without product)

1-Requires few spare parts

2- Has no seal in contact with the product

3- Can work at high temperatures (100 °C)

4-Few numbers of valves per volume unit

5-Collect the information from various resources and use the collected data to

formulate&solve the problem.



A furnace is charged with 100kmols of fuel gas,the composition of which is 50% CO,30% H2,5% CH4,5% C2H6 and 10% O2. Dry air is supplied 50% in excess combustion. Assuming complete combustion.


 1. Calculate the mass of NaOH required to prepare a one-liter solution with a molarity of 2.80. 2. A quantity of 5.25 grams of NaOH is dissolved in a sufficient amount of water to make exactly a one-liter solution. What is the molarity of this solution? 3. Calculate the molarity of a solution if 80.8 grams of calcium iodide is dissolved in 2250.0ml of water. 4. How many moles of magnesium chloride are present in 60.9ml of a 0.100M magnesium chloride solution? 5. How many grams of KOH are present in 35.0ml of a 5.50M solution?


1. The heat of combustion of 2-propanol at 298.15 K, determined in a bomb calorimeter, is -

33.41 kJ/g. For the complete combustion of one mole of 2-propanol, determine (a) ΔE, and (b)

ΔH.

2. A 1.397 g sample of thymol, C 10 H 14 O (s),is burned in a bomb calorimeter assembly. The temperature increase is 11.23°C, and the heat

capacity of the bomb calorimeter is 4.68 kJ/°C. What is the heat of combustion of thymol,

expressed in kJ/mol C 10 H 14 O?

3. The heat of solution of NaOH is -44.5 kJ/mol NaOH. To what maximum temperature may a sample

of water, originally at 21°C, be raised in the preparation of 500 mL of 7.0 M NaOH? Assume the

solution has a density of 1.08 g/mL and specific heat of 4.00 J/g°C.

4. Brass has a density of 8.40 g/cm 3 and a specific heat of 0.385 J/g°C. A 15.2 cm 3 piece of

brass at an initial temperature of 163°C is dropped into an insulated container with 150.0 g

water initially at 22.4°C. Find the final temperature of the brass-water mixture


Given the following data, calculate the ∆H for the reaction: CaC₂(s) + 2H₂O(l) → Ca(OH)₂(aq) + C₂H₂(g).


Data:

Ca(s) + 2C(graphite) -> CaC2(s) delta H= -62.8 kJ

Ca(s) + 1/2O2(g) -> CaO(s) delta H= -635.5 kJ

CaO(s) +H2O(l) -> Ca(OH)s (aq) delta H= -653.1 kJ

C2H2(g) + 5/2O2(g) -> 2CO2(g) + H2O(l) delta H= -1300. kJ

C(graphite) + O2(g) -> CO2(g) delta H= -393.5 kJ



The Destruction of Jericho The Bible describes the Exodus

as a period of 40 years that began with plagues in Egypt

and ended with the destruction of Jericho. Archeologists

seeking to establish the exact dates of these events have

proposed that the plagues coincided with a huge eruption

of the volcano Thera in the Aegean Sea.

a. Radiocarbon dating suggests that the eruption occurred

around 1360 bce, though other records place the

eruption of Thera in the year 1628 bce. What is the

percent difference in the 14C decay rate in biological

samples from these two dates?



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