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Carry out the following operations as if it were a calculation of real experimental results. Express the answer with the correct number of significant figures.

 

(3.26 × 10−3 mg ) − (7.88 × 10−5 mg )


Consider the equilibrium 2I(g) Δ I2(g) What would be the effect on the position of equilibrium of (a) increasing the total pressure on the system by decreasing its volume; (b) adding gaseous I2 to the reaction mixture; and (c) decreasing the temperature at constant volume?


A 2L solution is prepared by dissolving 16.4g of Ca(NO3)2 in water. What is the molar concentration of nitrate ion?
Refer to approximate tables (from chemistry handbooks) for the actual values of specific heats. How do you account for the large deviations from actual values?
Calculate the osmotic pressure at 20C of an aqueous solution containing 5.0 g of sucrose, C12H22O11, in 100.0 mL of solution.
A 0.205-g sample of white phosphorus was dissolved in 25.0 g of carbon disulfide, CS2. The boiling-point elevation of the carbon disulfide solution was found to be 0.159C. What is the molecular mass of the phosphorus in solution? What is the formula of molecular phosphorus?
A 0.930-g sample of ascorbic acid (vitamin C) was dissolved in95.0g of water. The concentration of ascorbic acid,as determined by freezing-pointdepression,was 0.0555 m. What is the molecular mass of ascorbic acid?
How many grams of ethylene glycol, CH2OHCH2OH, must be added to 37.8 g of water to give a freezing point of 0.150C?

Calculate E o for the following cells: a) Cl2/ClO3 - //O2/H2O b) OH- /O2//ClO3 - /Cl- (basic medium)


 A 0.5-g sample of TNT(C7H5N2O6) is burned in a bomb calorimeter containing 610 g of water at an initial temperature of 20°C. The heat capacity of the bomb is 420 J/°C and the heat of combustion of TNT is 3374 kJ/mol. Calculate the final temperature of the water and calorimeter once the reaction is complete.


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