Solution.
2HClO4 + Ba(OH)2 = Ba(ClO4)2 + 2H2O
n(Ba(OH)2) = 0.0046 moles
n(HClO4) = 0.0092 moles
C = 0.0092/0.05 = 0.185 M (=0.2 M)
Answer. 0.185 M
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