1. Ammonium sulfate is a salt of a strong acid and a weak base. hence on dissolving it in water, hydrolysis of cation takes place creating equilibrium(equ.) between NH4+ and NH4OH with NH4OH itself maintaining the solubility equ. in water with NH3 and H2O, giving solution a slight ammoniacal smell.also hydrolysis of ammonium ion leads to the formation of hydronium ions(hydrated H+ ions) making solution acidic and obviously sulphate ion is present as it is in the solution.
2. Ethanol has a polar -OH group, which hydrogen bonds to water, which makes ethanol soluble.
3. Methane is prsctically insoluble in water.
4. Methane is well soluble in n-hexane.
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