Question #68839

Two cells A and B are connected in series to a supply of electricity and 0.04 faraday of electricity are passed through each cell, each cell contains an aqeous solution of copper II tetraoxosulphate VII of the same concentration but cell A has copper electrodes and cell B has platinum electrode what happens at the anode in A and the cathode in B?
Also if cathode A as increased in mass by 1.25g, calculate the mass which would have been deposited by one Faraday of electricity at A.

Expert's answer

Answer on Question # 68839, Chemistry / General Chemistry

1) Two cells A and B are connected in series to a supply of electricity and 0.04 faraday of electricity are passed through each cell, each cell contains an aqueous solution of copper II tetraoxosulphate VII of the same concentration but cell A has copper electrodes and cell B has platinum electrode what happens at the anode in A and the cathode in B?

2) Also if cathode A as increased in mass by 1.25g, calculate the mass which would have been deposited by one Faraday of electricity at A.

Solution:

1) Anode:


CuSO4⇆Cu2++SO42−CuSO_4 \leftrightarrows Cu^{2+} + SO_4^{2-}Cu2++2eˉ⇒CuCu^{2+} + 2\bar{e} \Rightarrow Cu


2) 2H2O⇒O2↑+4H+2H_2O \Rightarrow O_2 \uparrow + 4H^+

2)


m=1.25 g×1 Faraday0.04 Faraday=31.25 (g)m = \frac{1.25\ g \times 1\ Faraday}{0.04\ Faraday} = 31.25\ (g)


Answer: 31.25 g.


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