What is the concentration of Br- in a solution prepared by mixing 0.500 L of 0.0450 M KBr and 0.250 L of 0.0250 M CaBr2?
Solution:
Moles of solute = Molarity × Liters of solution
Therefore,
Moles of KBr = (0.0450 M) × (0.500 L) = 0.0225 mol
Moles of CaBr2 = (0.0250 M) × (0.250 L) = 0.00625 mol
KBr and CaBr2 are strong electrolytes that completely dissociate in solution.
KBr(aq) → K+(aq) + Br−(aq)
According to stoichiometry: Moles of Br− = Moles of KBr = 0.0225 mol
CaBr2(aq) → Ca2+(aq) + 2Br−(aq)
According to stoichiometry: Moles of Br− = 2 × Moles of CaBr2 = 2 × 0.00625 mol = 0.0125 mol
Total number of Br− moles = (0.0225 mol + 0.0125 mol) = 0.0350 mol
Total liters of solution = (0.500 L + 0.250 L) = 0.750 L
Thus,
Concentration of Br− = (0.035 mol / 0.750 L) = 0.0467 M
Answer: The concentration of Br− in a solution is 0.0467 M
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