The exothermic reaction of quicklime with water and the rather small specific heats of both
quicklime (0.946 J/g? °C) and slaked lime (1.20 J/g? °C) make it hazardous to store and
transport lime in vessels made of wood. Wooden sailing ships carrying lime would occasionally
catch fire when water leaked into the hold.
(a) If a 500 g sample of water reacts with an equimolar amount of CaO (both at an initial
temperature of 25°C), what is the final temperature of the product, Ca(OH)2? Assume that
the product absorbs all of the heat released in the reaction.
(b) Given that the standard enthalpies of formation of CaO and H2O are 2635.6 kJ/mol and
2285.8 kJ/mol, respectively, calculate the standard enthalpy of formation of Ca(OH)2.
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