The question requirements is to get the mole fraction of the solution
Xsolution=1
But adjusting the condition of the question to read;
" Calculate the mole fraction of each component of a solution containing 85g ethanol in 500g of water"
Solution
XA=nA+nBnA
Where XA is mole fraction of A
nA= Moles of A
nB= Moles of B
nwater=18500=27.7778
Molar mass of ethanol =46g/mol
nethanol=4685=1.8478
Total moles =27.7778+1.8478=29.6256
Xwater=29.625627.7778=0.9376
Xethanol=29.62561.8478=0.0624
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