Question #258622

Calculate the standard enthropy change to produce synthesis gas




CO(g) + H2(g) -> CH4(g) + H2O(g)

1
Expert's answer
2021-10-30T01:13:24-0400

CO(g) + 3H2(g) → CH4(g) + H2O(g)

We know the ΔH0:


ΔH0=ΔHproducts0ΔHreactants0=[ΔH0CH4(g)+ΔH0H2O(g)][ΔH0H2(g)+ΔH0CO(g)]=[74.6+(241.8)][3×0+(110.5)]=316.4+110.5=205.9  kJΔH^0 = \sum ΔH^0_{products} -\sum ΔH^0_{reactants} \\ = [ΔH^0 CH_4 (g) + ΔH^0 H_2O (g)] – [ΔH^0 H_2 (g) + ΔH^0 CO(g)] \\ = [-74.6 +(-241.8)] -[3 \times 0 + (-110.5)] \\ = -316.4 +110.5 \\ = -205.9 \;kJ


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