Answer to Question #149845 in General Chemistry for taiya

Question #149845
What mass of O2 is needed to increase the temperature of 35 grams polyethylene from 250K to 375. K? (specific heat of polyethylene is 0.551 cal/gK)
P4 + 5O2 --> P4O10 ∆H = - 3013 kJ/mol
1
Expert's answer
2020-12-10T07:47:09-0500

First calculate the amount of heat needed to increase the temperature of 35 grams of polyethylene from 250K to 375K:

Q=cmΔT=0.55135(375250)=2410.6(cal)Q = cm\Delta T = 0.551 * 35 * (375-250) = 2410.6 (cal)

Convert calories to joules (1 cal = 4.184 J):

Q=2410.64.184=10086(J)=10.09(kJ)Q = 2410.6 * 4.184 = 10086 (J) = 10.09 (kJ)

Find the mass of O2 needed to produce 3013 kJ of heat (5 moles according to the equation):

m(O2)=Mν=325=160(g)m(O_2) = M*\nu = 32 * 5 = 160 (g)

If 160 g of Oare needed to produce 3013 kJ of heat, then calculate the amount of NO2 needed to produce 10.09 kJ of heat:

m(O2)=16010.09/3013=0.536(g)m(O_2) = 160 * 10.09/3013 = 0.536 (g)

Answer: 0.536 g of O2 is needed to increase the temperature of 35 grams of polyethylene from 250K to 375K.



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