First calculate the amount of heat needed to increase the temperature of 35 grams of polyethylene from 250K to 375K:
"Q = cm\\Delta T = 0.551 * 35 * (375-250) = 2410.6 (cal)"
Convert calories to joules (1 cal = 4.184 J):
"Q = 2410.6 * 4.184 = 10086 (J) = 10.09 (kJ)"
Find the mass of O2 needed to produce 3013 kJ of heat (5 moles according to the equation):
"m(O_2) = M*\\nu = 32 * 5 = 160 (g)"
If 160 g of O2 are needed to produce 3013 kJ of heat, then calculate the amount of NO2 needed to produce 10.09 kJ of heat:
"m(O_2) = 160 * 10.09\/3013 = 0.536 (g)"
Answer: 0.536 g of O2 is needed to increase the temperature of 35 grams of polyethylene from 250K to 375K.
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