First calculate the amount of heat needed to increase the temperature of a 333-gram block of iron from 22⁰C to 1300⁰C:
"Q = cm\\Delta T = 0.49 * 333 * (1300-22) = 208531 (J) = 208.5 (kJ)"
If 3 moles of NO2 are needed to produce 138 kJ of heat, then calculate the amount of NO2 needed to produce 208.5 kJ of heat:
"\\nu = 208.5*3\/138 = 4.53 (mol)"
Answer: 4.53 moles of NO2 are needed to increase the temperature of a 333-gram block of iron from 22⁰C to 1300⁰C.
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