Q142930
From a 0.5 M NaCl solution, prepare a 0.1M NaCl solution in a 250cm3 flask. Show all calculations
Solution:
0.5M NaCl solution is our stock solution and we have to prepare 250cm3 of 0.1M NaCl from it.
Method 1:
We can use the dilution equation, Mi Vi = Mf Vf and find the volume of stock solution required for preparing the dilute solution.
Mi = concentration of solution before dilution ( concentration of stock solution ) = 0.5 M NaCl
Vi = volume of stock solution required ( This is unknown to us) = ?
Mf = concentration of solution after dilution ( concentration of diluted solution ) = 0.1M NaCl
Vf = volume of diluted solution = 250cm3 .
Substitute all this information in the dilution formula we have
0.5 M NaCl * Vi = 0.1M NaCl * 250cm3 ;
divide both the side by 0.5 M NaCl, we have
0.5 M NaCl * Vi / 0.5 M NaCl = 0.1M NaCl * 250cm3 /0.5 M NaCl
Vi = 50 cm3 ;
Hence we will take 50 cm3 of 0.5 M NaCl solutuion in a 250 mL volumetric flask and dilute it with
distilled water upto the mark.
Method 2:
Here we will follow two steps.
Step 1: We can first find the moles of NaCl present in the 250 cm3 of 0.1M NaCl solution by using
formula of molarity.
Step 2: In this step we will again use the formula of molarity and find the volume using moles of NaCl and molarity of stock solution of NaCl .
Convert 250cm3 to 'L' using 1L = 1000 cm3 ;
volume of diluted solution in 'L' = 250cm3 * 1L/1000cm3 = 0.250 L;
Step 1: To find moles of NaCl required for preparing solution.
molarity = moles of NaCl / volume of NaCl in 'L'
0.1M = moles of NaCl / 0.250L ;
multiply both the side 0.250L, we have
0.1mol/L * 0.250L = moles of NaCl * 0.250L / 0.250L ;
0.0250 mol = moles of NaCl ;
Hence moles of NaCl required for preparing solution is 0.0250 moles
Step 2 : To find the volume of stock solution using moles and molarity of stock solution.
molarity = moles of NaCl / volume of NaCl in 'L' ;
0.5 M = 0.0250 moles / Vi ;
Solve this equation for Vi we have
Vi = 0.0250moles / 0.5mol/L = 0.050 L;
which in cm3 = 0.050 L * 1000cm3 / 1L = 50 cm3 ;
Hence we will take 50cm3 of stock solution in a 250 mL volumetric flask and divide it upto the mark.
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