Question #128909
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The equilibrium constant, Kc is calculated using molar concentrations. For gaseous reactions another form of the equilibrium constant, Kp calculated from partial pressures instead of concentrations. These two equilibrium constants are related by the equation
Kp=Kc(RT)^Δn
where R=8.314 L⋅kPa/(K⋅mol) T is the absolute temperature, and Δn is the change in the number of moles of gas (sum moles products - sum moles reactants). For example, consider the reaction.
For the reaction
3A(g)+2B(g)⇌C(g)
Kc= 72.2 at a temperature of 237 ∘C .Calculate the value of Kp
Thank you very much.
1
Expert's answer
2020-08-13T07:57:27-0400

Kp(equilibrium constant) is the relationship between the concentrations ofthe products and the reactants at equilibrium in relaton to partial pressures.K_p(equilibrium\ constant)\ is \ the\ relationship\ between\ the \ concentrations\ of\newline the\ products\ and \ the\ reactants \ at\ equilibrium\ in \ relaton\ to\ partial\ pressures.

Kp=Kc(RT)Δn  where,R=8.314LkPa/(Kmol) or0.08514L/K.molT=2370  or 510KΔn=mol product  mol of reactants. 15=4K_p=K_c(RT)^{\Delta n}\ \ where,\newline R=8.314L-kPa/(K-mol)\ or0.08514L/K.mol\newline T=237^0\ \ or\ 510K\newline \Delta n=mol\ product\ -\ mol\ of\ reactants.\ 1-5=-4


Kp=72.2 (0.08314510)4K_p=72.2\ *(0.08314*510)^{-4}


Kp=72.2  (3.1107)Kp=2.2105K_p=72.2\ *\ (3.1*10^{-7})\newline K_p=2.2*10^{-5}


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