a)The specific rotation, [a], of the racemate is expected to be 0, since the effect of one enantiomer cancel the other out, molecule for molecule.
Optical purity, % = 100 [a]mixture / [a]pure sample
= 100 (0) / +23.1o
= 0%
b) The negative sign tells indicates that the R enantiomer is the dominant one.
Optical purity, % = 100 [a]mixture / [a]pure sample
= 100 (-9.2) / -23.1o
= 40% it means 40% excess oc R over S
c)The 60% leftover, which is optically inactive, must be equal amounts of both (R)- and (S)-bromobutane. The excess 40% is all R so there is a total of 70% (R) and 30% (S)
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