Solution:
The balanced chemical equation:
Ba(OH)2 + (NH4)2SO4 = BaSO4 + 2NH3 + 2H2O
The molar mass of Ba(OH)2 is 171.34 g/mol
The molar mass of (NH4)2SO4 is 132.14 g/mol
The molar mass of BaSO4 is 233.38 g/mol
Solution path #1:
Use stoichiometry to calculate how much product is produced by each reactant (For example, BaSO4).
The reactant that produces the lesser amount of product is the limiting reactant: in this case is barium hydroxide - Ba(OH)2.
Solution path #2:
Calculate moles:
1) Moles of substance = Mass of substance / Molar mass of substance
2) Divide by coefficients of balanced equation:
barium hydroxide ⇒ 0.233 mol / 1 mol = 0.233
ammonium sulfate ⇒ 0.303 mol / 1 mol = 0.303
Barium hydroxide is the lower value. It is the limiting reagent.
Ba(OH)2 is the limiting reactant.
Answer: Ba(OH)2 is the limiting reactant.
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