Question #108488
1. Calculate the pH of a 1.09×10-2 M solution of the decongestant ephedrine hydrochloride if the pKb of ephedrine (its conjugate base) is 3.86.
1
Expert's answer
2020-04-14T01:43:20-0400

pKa+pKb=14pKa=143.86=10.14pK_a+pK_b=14\\pK_a=14-3.86=10.14

pH of a weak acid solution is log[CKa]=12(logC+logKa)=12logC+12pKa=12(1.96)+5.07=6.05-\log[\sqrt{CK_a}]=-\frac12(\log C+\log K_a)=-\frac12 \log C+\frac12pK_a=-\frac12(-1.96)+5.07=6.05


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