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a) Explain the following: i) Higher value of pka indicates a strong nucleophilic character. ii) A tertiary amine is more basic than a primary amine. iii) NO2 is a better electrophile as compared to NH4. iv) The nucleophilicity is different from the basicity. v) Isotopes have been used to study the reaction path and mechanism. b) Arrange the following carbocations in the order of increasing stability. i) (C6H5)3C + , C6H5 = C H2 , (C6H5)2CH, CH2 = CH-CH2 ii) In SN2 mechanism inversion of configuration takes place. Explain.
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