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5. a) By writing molecular orbital configuration for each of following molecules calculate the bond order and also determine whether it is paramagnetic or diamagnetic. (i) NO (ii) CO (iii) O2 + (6) b) Using suitable examples define gerade and ungerade orbitals. (4) 6. a) The dipole moment of HBr is 2.60 1030 C m and interatomic distance 141 pm. What is the percentage ionic character of HBr? (6) b) Draw all of the stereoisomers of 2,3-butandiol, label meso compounds and pairs of enantiomer. (2) c) What is the predicted magnetic moment of Cu+ and Cu2+ ions in B Unit (Atomic number of Cu 29)? (2) 7. a) Given that the spacing of the lines in the microwave spectrum of 24Al1H is constant at 12.604 cm1 . Calculate the moment of inertia and bond length of the molecule. (
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