Question #37529

WHAT IS THE DIFFERENCE BETWEEN DEGENERATE AND NON DEGENERATE ENERGY

Expert's answer

Answer on Question#37529, Physics, Quantum Mechanics

In order to solve Schrodinger's stationary equation Hψ=EψH\psi = E\psi , one has to find eigenfunctions (wave functions), in which every wave function (in each state respectively) gives a certain eigenvalue (energy). So to say, we obtain eigenstates ψn(q)\psi_{n}(q) for discrete spectrum and ψf(q)\psi_{f}(q) for continuous spectrum, and corresponding energies at that states. If one has one energy for each state, then energy levels are not degenerate. In case if there are NN eigenstates for one energy, it is said that energy level is NN times degenerate. For example, let us have a look at Hydrogen atom wave functions and energies (ignoring spin):

En=1n2E_{n} = -\frac{1}{n^{2}} and ψn=Rnl(r)Ylm(φ,θ)\psi_{n} = R_{nl}(r)Y_{lm}(\varphi ,\theta) . For fixed quantum number nn (fixed energy), quantum numbers might have values l=0..n1;m=l...ll = 0..n - 1;m = -l...l . There are n2n^2 different states (wave functions) for fixed energy level EnE_{n} . Hence, energy levels for Hydrogen atom are n2n^2 times degenerate.


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