What is the probability of finding a particle at centre of box in it's first excited state in a infinite potential well ??
The wave function of particle in the first excited state is
ψ(x)=2Lsin(2πxL)\psi(x)=\sqrt{\frac{2}{L}}sin(\frac{2\pi x}{L})ψ(x)=L2sin(L2πx)
The probability of finding a particle at centre of box is
P=∣ψ(x)∣2(L)P=|\psi(x)|^2(L)P=∣ψ(x)∣2(L)
=∣2Lsin(2π(x/2)L)∣2(L)=0=|\sqrt{\frac{2}{L}}sin(\frac{2\pi (x/2)}{L})|^2(L) =0=∣L2sin(L2π(x/2))∣2(L)=0 since sin(π)=0sin(\pi) =0sin(π)=0
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